National Single Crystal X-ray Facility, Utrecht University, The Netherlands

A complete list of publications can be found on the homepage of Crystal and Structural Chemistry:


M. Lutz, A.M.M. Schreurs, A.L. Spek, M.A.H. Moelands, R.J.M. Klein Gebbink
Acta Cryst. C66, m9 (2010); DOI: 10.1107/S0108270109053281

C. Zonta, O. De Lucchi, A. Linden, M. Lutz
Synthesis and Structure of D3h-Symmetric Triptycene Trimaleimide
Molecules 15, 226 (2010); DOI: 10.3390/molecules15010226

R. Angamuthu, P. Byers, M. Lutz, A.L. Spek, E. Bouwman
Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex
Science 327, 313 (2010); DOI: 10.1126/science.1177981

T.J. Mooibroek, E. Bouwman, M. Lutz, A.L. Spek, E. Drent
NMR Spectroscopic Studies of Palladium(II) Complexes of Bidentate Diphenylphosphane Ligands with Acetate and Tosylate Anions: Complex Formation and Structures
Eur. J. Inorg. Chem. 298 (2010); DOI: 10.1002/ejic.200900974

S.H. Wadman, R.W.A. Havenith, M. Lutz, A.L. Spek, G.P.M. van Klink, G. van Koten
Selective para-Halogenation and Dimerization of N,C,N'-Arylruthenium(II) and -(III) 2,2':6',2''-Terpyridine Cations
J. Am. Chem. Soc. 132, 1914 (2010); DOI: 10.1021/ja9073276

A. Fraix, M. Lutz, A.L. Spek, R.J.M. Klein Gebbink, G. van Koten, J.-Y.Salaün, P.-A. Jaffres
Construction of a monoanionic S,N,S-pincer ligand with a pyrrole core by sequential [1,2] phospho-Fries rearrangement. Characterization of palladium and silver coordination complexes
Dalton Trans. 39, 2942 (2010); DOI: 10.1039/b923351b

S. Bonnet, M. Lutz, A.L. Spek, G. van Koten, R.J.M. Klein Gebbink
Bimetallic SCS- and PCP-Pincer Ruthenium Palladium Complexes: Synthesis, Structure and Catalytic Activity
Organometallics 29, 1157 (2010); DOI: 10.1021/om900984t

E. Zuidema, P.E. Goudriaan, B.H.G. Swennenhuis, P.C.J. Kamer, P.W.N.M. van Leeuwen, M. Lutz, A.L. Spek
Phenoxaphosphine-Based Diphosphine Ligands. Synthesis and Application in the Hydroformylation Reaction
Organometallics 29, 1210 (2010); DOI: 10.1021/om901041r

B.M.J.M. Suijkerbuijk, D.M. Tooke, M. Lutz, A.L. Spek, L.W. Jenneskens, G. van Koten, R.J.M. Klein Gebbink
Synthesis of and Evidence for Electronic Communication within Heteromultimetallic Tetrakis(NCN-pincer metal)-(Metallo)porphyrin Hybrids
J. Org. Chem. 75, 1534 (2010); DOI: 10.1021/jo902402g

R. Scheffelaar, M. Paravidino, A. Znabet, R.F. Schmitz, F.J.J. de Kanter, M. Lutz, A.L. Spek, C. Fonseca Guerra, F.M. Bickelhaupt, M.B. Groen, E. Ruijter, R.V.A. Orru
Scope and Limitations of an Efficient Four-Component Reaction for Dihydropyridin-2-ones
J. Org. Chem. 75, 1723 (2010); DOI: 10.1021/jo902613j

J. Li, M. Lutz, A.L. Spek, G.P.M. van Klink, G. van Koten, R.J.M. Klein Gebbink
Chiral Amino Alcohol Derived Bis-phosphoramidite Pincer Palladium Complexes and Their Applications in Asymmetric Allylation of Aldimines
Organometallics 29, 1379 (2010); DOI: 10.1021/om100021p

M. Lutz, S. Smeets, P. Parois
Acta Cryst. E66, m671 (2010); DOI: 10.1107/S160053681001737X

P. Marques-Gallego, M.A. Gamiz-Gonzalez, F.R. Fortea-Perez, M. Lutz, A.L. Spek, A. Pevec, B. Kozlevcar, J. Reedijk
Quinoxaline-2-carboxamide as a carrier ligand in two new platinum(II) compounds: Synthesis, crystal structure, cytotoxic activity and DNA interaction
Dalton Trans. 39, 5152 (2010); DOI: 10.1039/c001158d

E.G. Ijpeij, B. Coussens, M.A. Zuideveld, G.H.J. van Doremaele, P. Mountford, M. Lutz, A.L. Spek
Synthesis, solid state and DFT structure and olefin polymerization capability of a unique base-free dimeric methyl titanium dication
Chem. Commun. 46, 3339 (2010); DOI: 10.1039/b925781k

J. Wassenaar, M. Kuil, M. Lutz, A.L. Spek, J.N.H. Reek
Asymmetric Hydrogenation with Highly Active IndolPhos-Rh Catalysts: Kinetics and Reaction Mechanism
Chem. Eur. J. 16, 6509 (2010); DOI: 10.1002/chem.200903476

M. Lutz, J. van Krieken
(S,S)-Lactoyllactic acid and (S,S,S)-lactoyllactoyllactic acid
Acta Cryst. C66, o401 (2010); DOI: 10.1107/S0108270110026193

S. Warsink, R.M. Drost, M. Lutz, A.L. Spek, C.J. Elsevier
Modular Synthesis of Bidentate Triazolyl-Functionalized N-Heterocyclic Carbenes and Their Palladium Complexes
Organometallics 29, 3109 (2010); DOI: 10.1021/om100435x

A.C. Carrasco, E.A. Pidko, A.M. Masdeu-Bulto, M. Lutz, A.L. Spek, D. Vogt, C. Müller
2-(2'-Pyridyl)-4,6-diphenylphosphine versus 2-(2'-pyridyl)-4,6-diphenylpyridine: an evaluation of their coordination chemistry towards Rh(I)
New J. Chem. 34, 1547 (2010); DOI: 10.1039/c0nj00030b

H. Jansen, F.B. Läng, J.C. Slootweg, A.W. Ehlers, M. Lutz, K. Lammertsma, H. Grützmacher
Synthesis, Structure, and Reactivity of a Stabilized Phosphiranylium Salt
Angew. Chem. 122, 5617 (2010); DOI: 10.1002/ange.201000901
Angew. Chem. Int. Ed. 49, 5485 (2010); DOI: 10.1002/anie.201000901

F.E. Genceli Guner, M. Lutz, T. Sakurai, A.L. Spek, T. Hondoh
Crystallization and Characterization of Magnesium Methanesulfonate Hydrate
Cryst. Growth Design 10, 4327 (2010); DOI: 10.1021/cg100234e

S. Bonnet, M.A. Siegler, J.H. van Lenthe, M. Lutz, A.L. Spek, G. van Koten, R.J.M. Klein Gebbink
Ruthenium-to-Platinum Interactions in NCN-Pincer Arene Heterobimetallic Complexes: An Experimental and Theoretical Study
Eur. J. Inorg. Chem. 4667 (2010); DOI: 10.1002/ejic.201000448

P.J.C. Hausoul, A.N. Parvulescu, M. Lutz, A.L. Spek, P.C.A. Bruijnincx, B.M. Weckhuysen, R.J.M. Klein Gebbink
Facile Access to Key Reactive Intermediates in the Pd/PR3-Catalyzed Telomerization of 1,3-Butadiene
Angew. Chem. 122, 8144 (2010); DOI: 10.1002/ange.201003090
Angew. Chem. Int. Ed. 49, 7972 (2010); DOI: 10.1002/anie.201003090

M. Lutz
Twinned low-temperature structures of tris(ethylenediamine)zinc(II) sulfate and tris(ethylenediamine)copper(II) sulfate
Acta Cryst. C66, m330 (2010); DOI: 10.1107/S0108270110041466

J. Li, M. Lutz, A.L. Spek, G.P.M. van Klink, G. van Koten, R.J.M. Klein Gebbink
Novel phosphite palladium complexes and their application in C-P cross-coupling reactions
J. Organomet. Chem. 695, 2618 (2010); DOI: 10.1016/j.jorganchem.2010.08.026

Y. Cabon, I. Reboule, M. Lutz, R.J.M. Klein Gebbink, B.-J. Deelman
Oxidative Addition of Sn-C Bonds on Palladium(0): Identification of Palladium-Stannyl Species and a Facile Synthetic Route to Diphosphinostannylene-Palladium Complexes
Organometallics 29, 5904 (2010); DOI: 10.1021/om1007067

D.J.M. Snelders, C. van der Burg, M. Lutz, A.L. Spek, G. van Koten, R.J.M. Klein Gebbink
Structure-Activity Relationships of Oligocationic Ammonium-Functionalized Triarylphosphines as Ligands in the Pd-Catalyzed Suzuki-Miyaura Reaction
ChemCatChem 2, 1425 (2010); DOI: 10.1002/cctc.201000232

T.J. Mooibroek, M. Lutz, A.L. Spek, E. Bouwman
Structure elucidation of the unprecedented asymmetric bis-chelate complex [Pd(1,3-bis(di(o-methoxy-m-methylphenyl)phosphino)propane)2]2+ in the solid state and in solution
Dalton Trans. 39, 11027 (2010); DOI: 10.1039/c0dt00699h

J. Li, M. Siegler, M. Lutz, A.L. Spek, R.J.M. Klein Gebbink, G. van Koten
PCN- and PCS-Pincer Palladium Complexes as Tandem Catalysts in Homoallylation Reactions
Adv. Synth. Catal. 352, 2474 (2010); DOI: 10.1002/adsc.201000204

R. Wolf, A.W. Ehlers, M.M. Khusniyarov, F. Hartl, B. de Bruin, G.J. Long, F. Grandjean, F.M. Schappacher, R. Pöttgen, J.C. Slootweg, M. Lutz, A.L. Spek, K. Lammertsma
Homoleptic Diphosphacyclobutadiene Complexes [M(P2C2R2)2]x- (M = Fe, Co; x = 0, 1)
Chem. Eur. J. 16, 14322 (2010); DOI: 10.1002/chem.201001913

B.M.J.M. Suijkerbuijk, D.J. Schamhart, H. Kooijman, A.L. Spek, G. van Koten, R.J.M. Klein Gebbink
Mono(NCN-pincer palladium)-metalloporphyrincatalysts: evidence for supramolecular bimetallic catalysis
Dalton Trans. 39, 6198 (2010); DOI: 10.1039/b925236n

M.A. Siegler, S. Bonnet, A.M.M. Schreurs, R.J.M. Klein Gebbink, G. van Koten, A.L. Spek
On the Two Closely Related Phases of [Ru(C5Me5)(1,3-(Me2NCH2)2C6H4)](BF4) and the Reversible Solid–Solid Order–Disorder Phase Transition
J. Chem. Cryst. 40, 753 (2010); DOI: 10.1007/s10870-010-9732-8

S.H. Wadman, D.M. Tooke, A.L. Spek, G.P.M. van Klink, G. van Koten
Cyclo-ruthenated and -platinated complexes bearing phosphonate substituents
Inorg. Chim. Acta 363, 1701 (2010); DOI: 10.1016/j.ica.2009.12.008

J. Wassenaar, E. Jansen, W.-J. van Zeist, F.M. Bickelhaupt, M.A. Siegler, A.L. Spek, J.N.H. Reek
Catalyst selection based on intermediate stability measured by mass spectrometry
Nature Chemistry 2, 417 (2010); DOI: 10.1038/nchem.614

G. Berthon-Gelloz, M.A. Siegler, A.L. Spek, B. Tinant, J.N.H. Reek, I.E. Marko
IPr* an easily accessible highly hindered N-heterocyclic carbene
Dalton Trans. 39, 1444 (2010); DOI: 10.1039/b921894g

J. Meeuwissen, A.J. Sandee, B. de Bruin, M.A. Siegler, A.L. Spek, J.N.H. Reek
Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde
Organometallics 29, 2413 (2010); DOI: 10.1021/om901028z

Y. Cabon, H. Kleijn, M.A. Siegler, A.L. Spek, R.J.M. Klein Gebbink, B.-J. Deelman
Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands
Dalton Trans. 39, 2423 (2010); DOI: 10.1039/b924783c

J. Wassenaar, B. de Bruin, M.A. Siegler, A.L. Spek, J.N.H. Reek, J.I. van der Vlugt
Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand
Chem. Commun. 46, 1232 (2010); DOI: 10.1039/b917632b

J. Wassenaar, M.A. Siegler, A.L. Spek, B. de Bruin, J.N.H. Reek, J.I. van der Vlugt
Versatile New C3-Symmetric Tripodal Tetraphosphine Ligands; Structural Flexibility to Stabilize CuI and RhI Species and Tune Their Reactivity
Inorg. Chem. 49, 6495 (2010); DOI: 10.1021/ic100221w

M. Rubio, M.A. Siegler, A.L. Spek, J.N.H. Reek
Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies
Dalton Trans. 39, 5432 (2010); DOI: 10.1039/c003352a

C.J. Arnusch, J.H. Ippel, H. Kooijman, A.L. Spek, R.M.J. Liskamp, J. Kemmink, R.J. Pieters
Direct Structural Comparison of a Rigid Cyclic Peptidic Scaffold Using Crystallography and NMR in Strained PH Polymer Gels
Eur. J. Org. Chem. 4501 (2010); DOI: 10.1002/ejoc.201000440

J. Meeuwissen, R. Detz, A.J. Sandee, B. de Bruin, M.A. Siegler, A.L. Spek, J.N.H. Reek
Ureaphosphanes as Hybrid, Anionic or Supramolecular Bidentate Ligands for Asymmetric Hydrogenation Reactions
Eur. J. Inorg. Chem. 2992 (2010); DOI: 10.1002/ejic.201000213

R.W.W. Hooft, L.H. Straver, A.L. Spek
Using the t-distribution to improve the absolute structure assignment with likelihood calculations
J. Appl. Cryst. 43, 665 (2010); DOI: 10.1107/S0021889810018601